Structure & Properties of Water (College Board AP® Biology): Study Guide

Naomi Holyoak

Written by: Naomi Holyoak

Reviewed by: Lára Marie McIvor

Updated on

Polarity & hydrogen bonding in water

  • The structure of a biological molecule determines its properties; differences in structure may include:

    • the components from which a molecule is built

    • the sequence in which the components occur

  • Within the structure of water molecules the electrons are shared unequally between oxygen and hydrogen; the oxygen atom has a partial negative charge (𝛿-) and the hydrogen atoms have a partial positive charge (𝛿+)

  • The unequal distribution of charge means that water is a polar molecule

  • The polar nature of water allows weak forces of attraction known as hydrogen bonds to form

Diagram showing hydrogen bonding between two water molecules, with partial charges indicated, and a label pointing to the bond.
Water is a polar molecule, meaning that hydrogen bonds form between oxygen and hydrogen atoms
  • The hydrogen bonds between water molecules provide water with properties that are essential to living systems

The properties of water

  • The polar nature of water molecules and the resulting hydrogen bonds provide water with some unusual properties

  • Examples of properties that are essential for the survival of living organisms include:

    • cohesion

    • adhesion

Cohesion

  • Cohesion can be defined as:

Forces of attraction between molecules of the same type

  • Cohesion means that water molecules are attracted to each other; examples of the importance of this property in living organisms include:

    • plant transport

      • Water molecules are drawn upwards behind other water molecules in the xylem due to cohesion

      • This provides plants with a water supply and enables the transport of dissolved mineral ions

    • surface tension

      • Cohesive forces mean that water molecules at the surface of a body of water are attracted to water molecules below the surface; this creates surface tension

      • Surface tension allows small organisms to live on the water's surface, e.g. pond skaters are small insects that walk on the surface of ponds and lakes

Adhesion

  • Adhesion can be defined as:

Attractive forces between molecules of a different type

  • Adhesion means that water molecules are attracted to other molecules

  • In plant transport this means that adhesion between water molecules and the xylem walls draws water upwards by capillary action

Diagram of water transport in xylem. Water molecules, shown as blue circles, move upwards, illustrating adhesion and cohesion by hydrogen bonding.
Water molecules move upwards in the xylem of plants due to cohesion and adhesion

Other properties of water

Property

Description

Importance for living organisms

High specific heat capacity

Hydrogen bonds reduce the movement of water molecules, meaning that a lot of energy is needed to raise the temperature of water

Water is thermally stable

High heat of vaporization

Hydrogen bonds mean that a lot of energy is needed to convert water from a liquid to a gas

Sweating and transpiration allow cooling by evaporation

Low density when frozen

Hydrogen bonds form an open lattice when water freezes, meaning that ice floats on water

Polar ice provides a habitat for some animals, and ice acts as an insulating layer over water

Solvent

Polar water molecules are attracted to charged particles in a solution, allowing ionic compounds, e.g. NaCl, to dissolve

Water can transport substances in a solution, and provides a medium for chemical reactions

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Naomi Holyoak

Author: Naomi Holyoak

Expertise: Biology

Naomi graduated from the University of Oxford with a degree in Biological Sciences. She has 8 years of classroom experience teaching Key Stage 3 up to A-Level biology, and is currently a tutor and A-Level examiner. Naomi especially enjoys creating resources that enable students to build a solid understanding of subject content, while also connecting their knowledge with biology’s exciting, real-world applications.

Lára Marie McIvor

Author: Lára Marie McIvor

Expertise: Biology Lead

Lára graduated from Oxford University in Biological Sciences and has now been a science tutor working in the UK for several years. Lára has a particular interest in the area of infectious disease and epidemiology, and enjoys creating original educational materials that develop confidence and facilitate learning.