Radioactive Decay Equations
- In radioactive decay, the number of undecayed nuclei falls very rapidly, without ever reaching zero
- Such a model is known as exponential decay
- The graph of number of undecayed nuclei against time has a very distinctive shape:
Radioactive decay follows an exponential pattern. The graph shows three different isotopes each with a different rate of decay
- The key features of this graph are:
- The steeper the slope, the larger the decay constant λ (and vice versa)
- The decay curves always start on the y-axis at the initial number of undecayed nuclei (N0)
Equations for Radioactive Decay
- The number of undecayed nuclei N can be represented in exponential form by the equation:
N = N0 e–λt
- Where:
- N0 = the initial number of undecayed nuclei (when t = 0)
- N = number of undecayed nuclei at a certain time t
- λ = decay constant (s-1)
- t = time interval (s)
- The number of nuclei can be substituted for other quantities.
- For example, the activity A is directly proportional to N, so it can also be represented in exponential form by the equation:
A = A0 e–λt
- Where:
- A = activity at a certain time t (Bq)
- A0 = initial activity (Bq)
- The received count rate C is related to the activity of the sample, hence it can also be represented in exponential form by the equation:
C = C0 e–λt
- Where:
- C = count rate at a certain time t (counts per minute or cpm)
- C0 = initial count rate (counts per minute or cpm)
The exponential function e
- The symbol e represents the exponential constant
- It is approximately equal to e = 2.718
- On a calculator, it is shown by the button ex
- The inverse function of ex is ln(y), known as the natural logarithmic function
- This is because, if ex = y, then x = ln(y)
Worked example
Strontium-90 decays with the emission of a β-particle to form Yttrium-90.The decay constant of Strontium-90 is 0.025 year -1. Determine the activity A of the sample after 5.0 years, expressing the answer as a fraction of the initial activity A0.
Step 1: Write out the known quantities
-
- Decay constant, λ = 0.025 year -1
- Time interval, t = 5.0 years
- Both quantities have the same unit, so there is no need for conversion
Step 2: Write the equation for activity in exponential form
A = A0 e–λt
Step 3: Rearrange the equation for the ratio between A and A0
Step 4: Calculate the ratio A/A0
Therefore, the activity of Strontium-90 decreases by a factor of 0.88, or 12%, after 5 years