Exponential Decay Graph for Capacitors
- To verify if potential difference, V, or charge, Q, on a capacitor decreases exponentially:
- Constant ratio method: Plot a V-t graph and check the time constant is constant, or check if the time to halve from its initial value is constant
- Logarithmic graph method: Plot a graph of ln V against t and check if a straight line graph is obtained
Constant Ratio Method
- A general form of the exponential decay question is given by
- Where A is a constant
- This equation shows that when t = A−1 the value of x will have decreased to approximately 37% of its original value, x0:
- Comparing this to the discharge equation for a capacitor:
- Therefore, for a discharging capacitor, when t = τ the potential difference on the capacitor will have decreased to approximately 37% of its original value
- This means that equal intervals of time give equal fractional changes of in potential difference
The graph of voltage-time for a discharging capacitor showing the positions of the first three time constants
- Hence, to validate if potential difference across a capacitor decreases exponentially:
The time constant, or the time taken for the potential difference to decrease to 37% of its original value, will be constant
- To find the time constant from a voltage-time graph, calculate 0.37V0 and determine the corresponding time for that value
The time constant shown on a charging and discharging capacitor
Logarithmic Graph Method
- The potential difference (p.d) across the capacitance is defined by the equation:
- Where:
- V = p.d. across the capacitor (V)
- V0 = initial p.d. across the capacitor (V)
- t = time (s)
- e = exponential function
- R = resistance of the resistor (Ω)
- C = capacitance of the capacitor (F)
- Rearranging this equation for ln(V) by taking the natural log (ln) of both sides:
- Comparing this to the equation of a straight line: y = mx + c
- y = ln (V)
- x = t
- gradient = −1/RC
- c = ln (V0)
A straight-line logarithmic graph of ln V against t can be used to verify an exponential relationship
Worked example
A student investigates the relationship between the potential difference and the time it takes to discharge a capacitor. They obtain the following results:
The capacitor is labelled with a capacitance of 4200 µF.
Calculate the value of the capacitance of the capacitor discharged.
Step 1: Complete the table
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- Add an extra column ln(V) and calculate this for each p.d.
Step 2: Plot the graph of ln(V) against average time t
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- Make sure the axes are properly labelled and the line of best fit is drawn with a ruler
Step 3: Calculate the gradient of the graph
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- The gradient is calculated by:
Step 4: Calculate the capacitance, C