Emission & Absorption Spectra in Stars (AQA A Level Physics)
Revision Note
Emission & Absorption Spectra in Stars
There are three types of light spectra:
Continuous emission spectra
Emission line spectra
Absorption line spectra
Continuous spectrum: created when photons of all wavelengths are emitted
Appearance: a broad range of colours (depending on a star's temperature)
Produced by: hot, dense sources, such as the cores of stars
Emission spectrum: created when photons are emitted by excited electrons in a hot gas
Appearance: discrete wavelengths represented by coloured lines on a black background
Produced by: hot, low-pressure gases, such as a nebula surrounding a star
Absorption spectrum: created when photons are absorbed by electrons in a cool gas
Appearance: discrete wavelengths represented by dark lines on a continuous spectrum
Produced by: light passing through cool, low-pressure gases, such as the photosphere of a star
Note: the lines in an absorption spectrum correspond to the same lines in the emission spectrum of the same element
The difference between continuous, emission & absorption spectra
An absorption spectrum is the combination of an emission spectrum on top of a continuous spectrum
Chemical Composition of a Star
Stellar spectral lines are caused by the interactions between photons and the atoms present in gaseous layers of stars
Photons produced by fusion reactions in a star’s core move towards the layers of gas in the outer atmosphere of the star
The photons produced in the core form a continuous spectrum
Photons are absorbed by the gas atoms, which excite and re-emit other photons of various frequencies in random directions
An absorption line will appear in a spectrum if an absorbing material is placed between a source and the observer
Each gas produces a unique pattern of spectral lines due to the specific transition between the element’s energy levels
The presence of absorption lines in a star’s spectrum act as fingerprints
They can be used to determine the presence of a certain element within the star
The chemical composition of a star can be investigated even when extremely distant
If the element is present in the star, its characteristic pattern of spectral lines will appear as dark lines in the absorption line spectrum of the star
The Sun is predominantly made up of hydrogen and helium gas
This can be verified by comparing the emission line spectra of hydrogen and helium with the absorption line spectrum of the Sun
The Hydrogen Spectrum
Each element produces its own unique set of lines corresponding to specific energy level transitions
The spectrum of hydrogen was the first to be studied in great detail
The full hydrogen spectrum
In spectra of hydrogen:
The Lyman series converges on the ground state n = 1
The Balmer series converges on the second energy level n = 2
The Ritz-Paschen converges on the third energy level n = 3, and so on
The Lyman series photons will have the most energy since they have the shortest wavelength
The Pfund series photons will have the least energy since they have the longest wavelength
Note: in this course, you only need to remember the Balmer series, the others are only mentioned here for context
Electron transitions in the hydrogen spectrum
The discovery of these electron transitions has enabled astronomers to study the nature and chemical composition of objects in the Universe
Worked Example
Which of the following electron transitions in a hydrogen atom would result in the emission of visible light?
A. n = 1 to n = 2
B. n = 2 to n = 3
C. n = 2 to n = 1
D. n = 3 to n = 2
Answer: D
A photon is emitted when an electron moves from a higher energy level to a lower energy level
This eliminates options A & B
Emission in the visible region occurs for an electron transitioning from any higher energy level to n = 2
Therefore, the transition n = 3 to n = 2 would result in the emission of visible light
Worked Example
Explain why:
(a) Hot, dense sources produce continuous spectra
(b) Hot, low pressure gases produce emission spectra
(c) Hot, dense sources observed through cool, low pressure gases produce absorption spectra
Answer:
Part (a)
Hot, dense sources, such as the cores of stars, produce continuous spectra because:
In a hot, dense material, the atoms or molecules are so close together that they interact with one another
This leads to a spread of energy states that are not clearly defined
Therefore, photons of all frequencies are emitted leading to an uninterrupted band of colour
Part (b)
Hot, low pressure gases produce emission line spectra, because:
Hot gases produce emission line spectra when photons are emitted due to the transition of electrons between discrete energy levels in atoms of the gas
The line spectrum has certain, fixed frequencies related to the differences in energy between the various energy levels of the atoms of the gas
In a low pressure gas, the atoms or molecules are not close together
This means the energy levels of the gas atoms or molecules are clearly quantised and well-defined
Therefore, only photons which correspond to the differences in energy between the energy levels of a bound electron are seen
Part (c) Hot, dense sources observed through cold gases produce absorption spectra because:
Atoms of different elements in the cold gas absorb energy emitted from the hot source but only at particular energy values
These particular energy values correspond to the differences in energy between the energy levels of a bound electron
This means that particular frequencies of light are absorbed, creating black lines in the continuous emission spectrum
Examiner Tips and Tricks
Given an absorption line spectrum for a specific star, you can be asked to identify a star of similar chemical composition. It is important to pay attention to the spacing between the lines to be able to correctly identify the most similar star to the given one.
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