Decay Equations (AQA A Level Physics)
Revision Note
Changes in N and Z by Radioactive Decay
There are four reasons why a nucleus might become unstable, and these determine which decay mode will occur
Too many neutrons = beta-minus emission
Too many protons = beta-plus emission or electron capture
Too many nucleons = alpha emission
Too much energy = gamma emission
If there are too many neutrons...
Beta-minus (β-) emission occurs
One of the neutrons in the nucleus changes into a proton and a β- particle (an electron) and antineutrino is released
The nucleon number is constant
The neutron number (N) decreases by 1
The proton number (Z) increases by 1
The general decay equation for β- emission is:
Representing beta-minus decay graphically
If there are too many protons...
Beta-plus (β+) emission or electron capture occurs
In beta-plus decay:
A proton changes into a neutron and a β+ particle (a positron) and neutrino are released
In electron capture:
An orbiting electron is taken in by the nucleus and combined with a proton causing the formation of a neutron and neutrino
In both types of decay, the nucleon number stays constant
The neutron number (N) increases by 1
The proton number (Z) decreases by 1
The general decay equation for β+ emission is:
Representing beta-plus decay graphically
The decay equation for electron capture is:
If there are too many nucleons...
Alpha (α) emission occurs
An α particle is a helium nucleus
The nucleon number decreases by 4 and the proton number decreases by 2
The neutron number (N) decreases by 2
The proton number (Z) decreases by 2
The general decay equation for α emission is:
Representing alpha decay graphically
If there is too much energy...
Gamma (γ) emission occurs
A gamma particle is a high-energy electromagnetic radiation
This usually occurs after a different type of decay, such as alpha or beta decay
This is because the nucleus becomes excited and has excess energy
Representing Nuclear Processes Graphically
In summary, alpha decay, beta decay and electron capture can be represented on an N–Z graph as follows:
Representing nuclear processes graphically
Worked Example
Plutonium-239 is a radioactive isotope that contains 94 protons and emits α particles to form a radioactive isotope of uranium. This isotope of uranium emits α particles to form an isotope of thorium which is also radioactive.
(a) Write two equations to represent the decay of plutonium-239 and the subsequent decay of uranium.
(b) Predict the decay mode of the thorium isotope.
(c) Draw the decay chain from plutonium-239 to the daughter product of thorium decay on an N–Z graph.
Answer:
Part (a)
Step 1: Write down the general equation of alpha decay
Step 2: Write down the decay equation of plutonium into uranium
Step 3: Write down the decay equation of uranium into thorium
Part (b)
Plutonium, 239Pu
Number of neutrons: 239 – 94 = 145
Neutron-nucleon ratio: 145 / 239 = 0.607
Uranium, 235U
Number of neutrons: 235 – 92 = 143
Neutron-nucleon ratio: 143 / 235 = 0.609
Thorium, 231Th
Number of neutrons: 231 – 90 = 141
Neutron-nucleon ratio: 141 / 231 = 0.610
Thorium-231 is neutron-rich compared to uranium-235 and plutonium-239
Therefore, it must be a β– emitter
Part (c)
The key features to draw on an N–Z graph are:
Values for neutron number (N) on the vertical axis
Values for proton number (Z) on the horizontal axis
Labels for the isotopes eg. 239Pu, 235U, 231Th
Arrows showing the direction of the decay
Labels for the type of emission eg. α, β–
Examiner Tips and Tricks
Watch out for the vertical axis for the N-Z graph. Instead of N for number of neutrons this is sometimes labelled as N for nucleon number (total protons and neutrons) which means the decays will be represented slightly differently.
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