Decay Equations (AQA A Level Physics)

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Changes in N and Z by Radioactive Decay

  • There are four reasons why a nucleus might become unstable, and these determine which decay mode will occur
    1. Too many neutrons = beta-minus emission
    2. Too many protons = beta-plus emission or electron capture
    3. Too many nucleons = alpha emission
    4. Too much energy = gamma emission

If there are too many neutrons...

  • Beta-minus-) emission occurs
  • One of the neutrons in the nucleus changes into a proton and a β- particle (an electron) and antineutrino is released
  • The nucleon number is constant
    • The neutron number (N) decreases by 1
    • The proton number (Z) increases by 1
  • The general decay equation for β- emission is:

straight X presubscript straight Z presuperscript straight A space rightwards arrow space straight beta presubscript negative 1 end presubscript presuperscript 0 space plus space straight Y presubscript straight Z plus 1 end presubscript presuperscript straight A space plus space top enclose v subscript straight e

Beta Minus Decay Graph, downloadable AS & A Level Physics revision notes

Representing beta-minus decay graphically

If there are too many protons...

  • Beta-plus+) emission or electron capture occurs
  • In beta-plus decay:
    • A proton changes into a neutron and a β+ particle (a positron) and neutrino are released
  • In electron capture:
    • An orbiting electron is taken in by the nucleus and combined with a proton causing the formation of a neutron and neutrino
  • In both types of decay, the nucleon number stays constant
    • The neutron number (N) increases by 1
    • The proton number (Z) decreases by 1
  • The general decay equation for β+ emission is:

X presubscript Z presuperscript A space rightwards arrow space beta presubscript plus 1 end presubscript presuperscript 0 space plus space Y presubscript Z minus sign 1 end presubscript presuperscript A space plus space italic v subscript italic e

Beta Plus Decay Graph, downloadable AS & A Level Physics revision notes

Representing beta-plus decay graphically

  • The decay equation for electron capture is:

straight X presubscript straight Z presuperscript straight A space plus space straight e presubscript plus 1 end presubscript presuperscript 0 space space rightwards arrow space straight Y presubscript straight Z minus 1 end presubscript presuperscript straight A space plus space v subscript e

If there are too many nucleons...

  • Alpha (α) emission occurs
  • An α particle is a helium nucleus
  • The nucleon number decreases by 4 and the proton number decreases by 2
    • The neutron number (N) decreases by 2
    • The proton number (Z) decreases by 2
  • The general decay equation for α emission is:

straight X presubscript straight Z presuperscript straight A space rightwards arrow space straight alpha presubscript 2 presuperscript 4 space plus space straight Y presubscript straight Z minus 2 end presubscript presuperscript straight A minus 4 end presuperscript

Alpha Decay Graph, downloadable AS & A Level Physics revision notes

Representing alpha decay graphically

If there is too much energy...

  • Gamma (γ) emission occurs
  • A gamma particle is a high-energy electromagnetic radiation
  • This usually occurs after a different type of decay, such as alpha or beta decay
  • This is because the nucleus becomes excited and has excess energy

Representing Nuclear Processes Graphically

  • In summary, alpha decay, beta decay and electron capture can be represented on an N–Z graph as follows:

NZ Decay Graph, downloadable AS & A Level Physics revision notes

Representing nuclear processes graphically

Worked example

Plutonium-239 is a radioactive isotope that contains 94 protons and emits α particles to form a radioactive isotope of uranium. This isotope of uranium emits α particles to form an isotope of thorium which is also radioactive.

(a)
Write two equations to represent the decay of plutonium-239 and the subsequent decay of uranium.
(b)
Predict the decay mode of the thorium isotope.
(c)
Draw the decay chain from plutonium-239 to the daughter product of thorium decay on an N–Z graph.

Part (a)

Step 1: Write down the general equation of alpha decay

straight X presubscript straight Z presuperscript straight A space rightwards arrow space straight Y presubscript straight Z minus 2 end presubscript presuperscript straight A minus 4 end presuperscript space plus space straight alpha presubscript 2 presuperscript 4

Step 2: Write down the decay equation of plutonium into uranium

Pu presubscript 94 presuperscript 239 space rightwards arrow space straight U presubscript 92 presuperscript 235 space plus space straight alpha presubscript 2 presuperscript 4

Step 3: Write down the decay equation of uranium into thorium

straight U presubscript 92 presuperscript 235 space rightwards arrow space Th presubscript 90 presuperscript 231 space plus space straight alpha presubscript 2 presuperscript 4

Part (b)

  • Plutonium, 239Pu
    • Number of neutrons: 239 – 94 = 145
    • Neutron-nucleon ratio: 145 / 239 = 0.607

  • Uranium, 235U
    • Number of neutrons: 235 – 92 = 143
    • Neutron-nucleon ratio: 143 / 235 = 0.609

  • Thorium, 231Th
    • Number of neutrons: 231 – 90 = 141
    • Neutron-nucleon ratio: 141 / 231 = 0.610

  • Thorium-231 is neutron-rich compared to uranium-235 and plutonium-239
  • Therefore, it must be a β emitter

Part (c)WE - NZ Decay Graph, downloadable AS & A Level Physics revision notes

  • The key features to draw on an N–Z graph are:
    • Values for neutron number (N) on the vertical axis
    • Values for proton number (Z) on the horizontal axis
    • Labels for the isotopes eg. 239Pu, 235U, 231Th
    • Arrows showing the direction of the decay
    • Labels for the type of emission eg. α, β

Examiner Tip

Watch out for the vertical axis for the N-Z graph. Instead of N for number of neutrons this is sometimes labelled as N for nucleon number (total protons and neutrons) which means the decays will be represented slightly differently.

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Katie M

Author: Katie M

Expertise: Physics

Katie has always been passionate about the sciences, and completed a degree in Astrophysics at Sheffield University. She decided that she wanted to inspire other young people, so moved to Bristol to complete a PGCE in Secondary Science. She particularly loves creating fun and absorbing materials to help students achieve their exam potential.