Radioactive Decay (AQA A Level Physics)
Revision Note
Radioactive Decay
Radioactive decay is defined as:
The spontaneous disintegration of a nucleus to form a more stable nucleus, resulting in the emission of an alpha, beta or gamma particle
Radioactive decay is a random process, this means that:
There is an equal probability of any nucleus decaying
It cannot be known which particular nucleus will decay next
It cannot be known at what time a particular nucleus will decay
The rate of decay is unaffected by the surrounding conditions
It is only possible to estimate the proportion of nuclei decaying in a given time period
The random nature of radioactive decay can be demonstrated by observing the count rate of a Geiger-Muller (GM) tube
When a GM tube is placed near a radioactive source, the counts are found to be irregular and cannot be predicted
Each count represents a decay of an unstable nucleus
These fluctuations in count rate on the GM tube provide evidence for the randomness of radioactive decay
The variation of count rate over time of a sample radioactive gas. The fluctuations show the randomness of radioactive decay
Activity & The Decay Constant
Since radioactive decay is spontaneous and random, it is useful to consider the average number of nuclei that are expected to decay per unit time
This is known as the average decay rate
As a result, each radioactive element can be assigned a decay constant
The decay constant λ is defined as:
The probability that an individual nucleus will decay per unit of time
When a sample is highly radioactive, this means the number of decays per unit time is very high
This suggests it has a high level of activity
The activity A of a radioactive sample is defined as:
The average number of nuclei that decay per unit of time
It can be calculated using:
Where:
A = activity of the sample (Bq)
ΔN = number of decayed nuclei
Δt = time interval (s)
λ = decay constant (s-1)
N = number of nuclei remaining in a sample
The activity of a sample is measured in Becquerels (Bq)
An activity of 1 Bq is equal to one decay per second, or 1 s-1
This equation shows:
The greater the decay constant, the greater the activity of the sample
The activity depends on the number of undecayed nuclei remaining in the sample
The minus sign indicates that the number of nuclei remaining decreases with time
Worked Example
Radium is a radioactive element first discovered by Marie and Pierre Curie. They used the radiation emitted from radium-226 to define a unit called the Curie (Ci) which they defined as the activity of 1 gram of radium.
In a 1 g sample of radium-226, 2.22 × 1012 atoms decayed in 1 minute.
Another sample of radium-226 containing 3.2 × 1022 atoms had an activity of 12 Ci.
Calculate:
(a) the value of 1 Ci
(b) the decay constant of radium-226.
Answer:
Part (a)
Step 1: Write down the known quantities
Number of atoms decayed, ΔN = 2.22 × 1012 decays
Time, Δt = 1 minutes = 60 s
Step 2: Write down the activity equation
Step 3: Calculate the value of 1 Ci
decays s−1
Therefore, 1 Ci = 3.7 × 1010 Bq
Part (b)
Step 1: Write down the known quantities
Number of atoms, N = 3.2 × 1022
Activity, A = 12 Ci = 12 × (3.7 × 1010)
Step 2: Write down the activity equation
Step 3: Calculate the decay constant of radium
s−1
Therefore, the decay constant of radium-226 is 1.4 × 10–11 s–1 (2 s.f.)
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