The Kelvin Scale & Absolute Zero (AQA A Level Physics)
Revision Note
The Kelvin Scale & Absolute Zero
On the thermodynamic (Kelvin) temperature scale, absolute zero is defined as:
The lowest temperature possible. Equal to 0 K or -273.15 °C
It is not possible to have a temperature lower than 0 K
This means a temperature in Kelvin will never be a negative value
Absolute zero is defined s as:
The temperature at which the molecules in a substance have zero kinetic energy
This means for a system at 0 K, it is not possible to remove any more energy from it
Even in space, the temperature is roughly 2.7 K, just above absolute zero
Using the Kelvin Scale
To convert between temperatures θ in the Celsius scale, and T in the Kelvin scale, use the following conversion:
θ / °C = T / K − 273.15
T / K = θ / °C + 273.15
Conversion chart relating the temperature on the Kelvin and Celsius scales
The divisions on both scales are equal. This means:
A change in a temperature of 1 K is equal to a change in temperature of 1 °C
This is why when using the specific heat capacity equation
Q = mcΔθ
Δθ does not require the temperature to be in either unit
This is because the difference in temperature between two values whether in Kelvin or Celsius will be exactly the same
Worked Example
In many ideal gas problems, room temperature is considered to be 300 K. What is this temperature in Celsius?
Answer:
Step 1: Kelvin to Celsius equation
θ / °C = T / K − 273.15
Step 2: Substitute in value of 300 K
300 K − 273.15 = 26.85 °C
Examiner Tips and Tricks
If you forget in the exam whether it’s +273.15 or −273.15, just remember that 0 °C = 273.15 K. This way, when you know that you need to +273.15 to a temperature in degrees to get a temperature in Kelvin. For example: 0 °C + 273.15 = 273.15 K
You will not be penalised for using a rounded value of 273 K in your exam.
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