Diffraction Effects of Momentum (AQA A Level Physics): Revision Note

Exam code: 7408

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Diffraction effects of momentum

  • When electrons pass through a slit similar in size to their de Broglie wavelength, they exhibit diffraction, a property of waves

  • The regular spacing of atoms in a crystalline solid acts as a diffraction grating, scattering the electrons in a predictable manner

  • The observed diffraction pattern can be used to deduce the structure of the crystal producing that pattern

  • High energy electrons have a shorter wavelength and can therefore be used to look at the size of the nucleus of an atom (as opposed to the arrangement of atoms in a crystal)

  • The de Broglie wavelength tells us about the wave-particle relationship:

λ = hmv

  • Where:

    • λ = the de Broglie wavelength (m)

    • h = Planck’s constant (J s)

    • m = mass of the electron (kg)

    • v = velocity of the electron (m s–1)

Two electron diffraction patterns side by side. The higher accelerating voltage and momentum beam give rings of smaller radius, while a low accelerating voltage and momentum give longer wavelength and rings of larger radius.
Comparison of electron diffraction patterns at different values of momentum

Momentum of electrons

  • Momentum is equal to p = mv, so, from de Broglie's equation:

    • A smaller momentum will result in a longer wavelength

    • A larger momentum will result in a shorter wavelength

Kinetic energy of electrons

  • The speed of an electron can be increased by increasing the accelerating voltage (or potential difference)

  • If the electron speed, and therefore kinetic energy is increased, then:

    • The wavelength of the wave will decrease

    • The diffraction rings will appear closer together

  • The higher the kinetic energy of the electron, the higher its momentum hence the shorter its de Broglie wavelength

Radius of the diffraction pattern

  • The radius of the diffraction pattern depends on the wavelength:

    • The longer the wavelength, the more the light spreads out hence a larger radius is produced

    • The shorter the wavelength, the smaller the radius produced

  • Therefore, electrons with smaller momentum will produce a more diffuse diffraction pattern

Worked Example

Electrons are accelerated through a film of graphite. The electrons are accelerated through a potential difference of 4 kV. The spacing between the graphite atoms is 1.4 × 10−10 m.

Calculate the angle of the first minimum of the diffraction pattern.

[4]

Answer:

Step 1: Determine the kinetic energy gained by an electron

  • Kinetic energy gained through a potential difference of 4 kV = 4 keV = 4000 eV

Ek = 4000 × (1.6 × 10−19) = 6.4 × 10−16 J [1 mark]

Step 2: Determine the speed of the electron

Ek = 12mv2   ⇒  v = 2Ekm

v = 2 × (6.4 × 10−16)9.11 × 10−31 = 3.748 × 107 m s−1 [1 mark]

Step 3: Determine the de Broglie wavelength of the electron

λ = hp = hmv

λ = 6.63 × 10−34(9.11 × 10−31)(3.748 × 107) = 1.942 × 10−11 m [1 mark]

Step 4: Determine the angle of the first minimum

  • The diffraction grating equation is given by

d sin θ = nλ

  • For the first minimum, n = 12

sin θ = λ2d

sin θ = 1.942 × 10−112 × (1.4 × 10−10) = 0.0694

θ = sin−1 (0.0694) = 4.0° (2 s.f.) [1 mark]

Examiner Tips and Tricks

Take a look at the revision note on diffraction gratings if you aren't sure where the equation used in the final step of the worked example comes from

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Katie M

Author: Katie M

Expertise: Curriculum Expert

Katie has always been passionate about the sciences, and completed a degree in Astrophysics at Sheffield University. She decided that she wanted to inspire other young people, so moved to Bristol to complete a PGCE in Secondary Science. She particularly loves creating fun and absorbing materials to help students achieve their exam potential.

Tim

Reviewer: Tim

Expertise: Content Creator

Timothy graduated with a first class degree in Mathematics and Physics from the University of Warwick. After working as a postgraduate researcher, Timothy has worked as a content creator for various online revision platforms, creating physics resources for a range of levels and exam boards.