Optical Isomers (OCR A Level Chemistry)

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Optical Isomers & Chirality

Optical isomerism

  • Stereoisomers are molecules that have the same structural formula but have the atoms arranged differently in space
  • There are two types of stereoisomerism
    • Geometrical (E / Z)
    • Optical

  • A carbon atom that has four different atoms or groups of atoms attached to it is called a chiral carbon or chiral centre
    • Chira comes from a Greek word meaning hand, so we talk about these molecules having a handedness

  • Compounds with a chiral centre (chiral molecules) exist as two optical isomers which are also known as enantiomers
  • The enantiomers are non-superimposable mirror images of each other just like your left and right hand

An Introduction to AS Level Organic Chemistry Enantiomers and Chiral Centre, downloadable AS & A Level Chemistry revision notes

A molecule has a chiral centre when the carbon atom is bonded to four different atoms or group of atoms; this gives rises to enantiomers

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Richard

Author: Richard

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Richard has taught Chemistry for over 15 years as well as working as a science tutor, examiner, content creator and author. He wasn’t the greatest at exams and only discovered how to revise in his final year at university. That knowledge made him want to help students learn how to revise, challenge them to think about what they actually know and hopefully succeed; so here he is, happily, at SME.