Electrochemical Cells (Edexcel A Level Chemistry)

Measuring the EMF of a cell

• To measure a cell EMF you will need
  • Two small beakers, around 75 cm³ capacity
  • Strips of suitable metals such as copper, zinc, iron and silver
  • 1.0 mol dm^-3 solutions of the metal ions (nitrates, chlorides or sulfates depending on their solubility)
  • A high resistance voltmeter (usually a digital multimeter has this)
  • Two sets of wires with crocodile clips
  • A salt bridge consisting of a strip of filter paper soaked in saturated potassium nitrate

The experimental set up for measuring the EMF of a cell made of two metal / metal ion half cells

Steps in the procedure

• The strips of metals need to be freshly cleaned to remove any oxide coatings
  • This can be done with a piece of sandpaper

• To support the metals, it is easiest to have long strips that can be folded over the side of the beaker and held in place with the crocodile clips
• Fill up the beakers to about two thirds of the way with the metal ion solutions
• Using tongs, dip a strip of filter paper into a beaker of saturated potassium nitrate solution and then place it between the two beakers making sure the ends of the strip are well immersed in the solutions
• Connect the crocodile clips to the voltmeter, wait for a steady reading and record the measurement

Practical tips

• If you don't get a positive reading on the voltmeter swap the terminals around
• Voltmeters will have marked positive and negative terminals (usually in red and black, respectively), so when you get a positive reading this tells you the relative polarity of the metals in the cell
• Change the salt bridge each time, to prevent cross contamination of ions between half cells

Specimen Results

• Here is a set of typical results for this experiment

Specimen EMF Results (theoretical values) Table

 Analysis

• It is unlikely you will get very close to the theoretical results as these would be obtained under standard conditions which are hard to achieve in a school laboratory
• However, the relative EMF of cells you construct should match the theoretical values
• The higher the EMF, the larger the difference in reactivity ('electron pushing power') between the metals