Syllabus Edition

First teaching 2023

First exams 2025

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Degradable Polymers (CIE A Level Chemistry)

Exam Questions

33 mins4 questions
1a1 mark

This question is about hydrolysis of polymers.

What is meant by a hydrolysis reaction?

1b2 marks

Describe the reaction conditions and state what occurs to the polyester during acid hydrolysis.

1c2 marks

Outline the difference in the product(s) between acid and base hydrolysis of a polyester.

1d4 marks

Draw structures for the products of acid and base hydrolysis of the following polymer:


6-6_q3d-ocr-a-as--a-level-easy-sq

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1a3 marks

Nylon is an example of a synthetic polyamide and contains the same links as polypeptides. Nylon is the general name for a family of polyamides. A section of a nylon polymer is shown in Fig. 1.1.

aqa-chemistry-trial-june

Fig. 1.1
 

i)
Draw the structures of two monomers that could be used to make this nylon.
 
[2]
ii)
State the type of polymerisation involved in the formation of this nylon.
 
[1]
1b5 marks

Nylon can be used to make clothing. Suggest why nylon should be protected from spillages of strong acids and alkalis.

1c2 marks

Nomex shown in Fig. 1.2 has a higher melting point than nylon and is used to make the flame resistant body suits worn by racing drivers. 

Suggest a reason why the melting point of Nomex is higher than that of nylon.

10

Fig. 1.2

1d3 marks
i)
Draw the two monomers that are used to manufacture Nomex










 

[2]

ii)
State the formula of any by-products produced. 
[1]

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2a3 marks
i)
Name an example of a synthetic polyester and a synthetic polyamide.
 
polyester
 
[1]
 
polyamide
 
[1]
 
ii)
Polyesters and polyamides are formed by condensation reactions.
 
Name a molecule which is commonly eliminated in such reactions.
 
[1]
2b2 marks

Table 2.1 shows the repeat units of a number of polymers. Place a tick () against the ones which are biodegradable.

Table 2.1

7-7-4b-m--polymer

2c2 marks

Draw the structures of two monomers used to form polymer B.

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3a1 mark

A section of polypeptide was hydrolysed and the amino acids in Table 3.1 were identified.

Table 3.1

Amino Acid Formula
T CH3CH(NH2)CO2H
U C6H5CH2CH(NH2)CO2H
V H2N(CH2)4CH(NH2)CO2H

Which of the amino acids T, U or V has the highest pH in an aqueous solution? Explain your answer.

Amino acid .............................

3b1 mark

State how many different dipeptides could be formed from a reaction mixture consisting of amino acids T and U.

3c2 marks

Polypeptides contain a high proportion of carbon and hydrogen in their structures, yet many are soluble in water. By referring to the structure of a polypeptide, explain why.

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