Nomenclature of Compounds (Cambridge (CIE) A Level Chemistry): Revision Note

Richard Boole

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Nomenclature of Aliphatic Compounds (AL)

  • Students are required to use systematic nomenclature of simple aliphatic compounds

  • The following method can be applied when naming organic compounds:

    • Identify the longest carbon chain containing the functional group

    • Identify the functional group on the chain to determine the suffix or prefix on the compound

    • Count along the carbon chain such that the functional group has the lowest number

    • Add any side chains or lower priority functional groups as prefixes to the beginning of the name in alphabetic order

    • Use the prefixes di-, tri- and tetra- if there are two or more identical functional groups or side chains

Nomenclature of simple aliphatic organic molecules with functional groups table

Functional group

Example

Name

Acyl chloride

 

propanoyl-chloride-highlighting-functional-group

 

Propanoyl chloride

Amine

 

dimethylamine-highlighting-functional-group

 

Dimethylamine

Amide

 

propanamide-highlighting-functional-group

 

Propanamide

Amino acid

 

2-aminoethanoic-acid-highlighting-functional-group

 

2-aminoethanoic acid

Nomenclature of Aromatic Compounds

  • The method used to name aromatic compounds is similar to that of aliphatic compounds

  • Students are required to use systematic nomenclature of simple aromatic molecules with one benzene ring and one or more simple substituents

Nomenclature of simple aromatic organic molecules with functional groups table

Functional group

Example

Name

Arene

 

propylbenzene-highlighting-functional-group

 

Propyl benzene

Chlorobenzene

 

2-methylchlorobenzene-highlighting-functional-group

 

2-methylchlorobenzene

Phenol

 

23-dimethyl-phenol-highlighting-functional-group

 

2,3-dimethyl phenol

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Richard Boole

Author: Richard Boole

Expertise: Chemistry

Richard has taught Chemistry for over 15 years as well as working as a science tutor, examiner, content creator and author. He wasn’t the greatest at exams and only discovered how to revise in his final year at university. That knowledge made him want to help students learn how to revise, challenge them to think about what they actually know and hopefully succeed; so here he is, happily, at SME.