Hydrocarbons & Alkanes (Cambridge (CIE) A Level Chemistry)
Revision Note
Hydrocarbons
Organic chemistry is the chemistry of carbon compounds
Carbon forms a vast number of compounds because it can form strong covalent bonds with itself
This enables it to form long chains of carbon atoms, branched chains or cycles, and hence an almost infinite variety of carbon compounds are known
Carbon always forms four covalent bonds which can be single, double or triple bonds
Examples of carbon structures
There is an almost infinite variety of chains, branches and rings able to form
A functional group is a specific atom or group of atoms which confer certain physical and chemical properties onto the molecule
Organic molecules are classified by the dominant functional group on the molecule
Organic compounds with the same functional group, but with each successive member different by CH2 are called a homologous series
Every time a carbon atom is added to the chain, two hydrogen atoms are also added, which is why the successive members differ by CH2
Hydrocarbons are compounds that are made up of carbon and hydrogen atoms ONLY
Examples of hydrocarbons
Ethanol is NOT a hydrocarbon as the molecule also contains an oxygen atom and is not solely made up of carbon and hydrogen
Examiner Tips and Tricks
You must state that hydrocarbons are ‘only’ made up of C and H atoms if defining this term in an exam
Alkanes
A functional group is an atom or a group of atoms in an organic molecule, which determines the physical and chemical properties of the molecule
Alkanes are the simplest hydrocarbons with no functional group
They are made up of carbon and hydrogen atoms bonded to each other with single covalent bonds
Different types of alkanes
Alkanes are compounds made up of carbon and hydrogen atoms only and contain no functional group
Homologous Series of Alkanes Table
Name of alkane | Number of carbons | Chemical formula | Boiling point in °C | State at room temperature | Melting point in °C |
---|---|---|---|---|---|
Methane | 1 | CH4 | -162 | gas | -183 |
Ethane | 2 | C2H6 | -89 | gas | -172 |
Propane | 3 | C3H8 | -42 | gas | -188 |
Butane | 4 | C4H10 | 0 | gas | -138 |
Pentane | 5 | C5H12 | 36 | liquid | -130 |
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