Reactions of Group 2 Elements (CIE A Level Chemistry)

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Reactions of Group 2 Elements

  • The Group 2 elements react with oxygen, water and dilute acids

Reaction of Group 2 elements table

Group 2 element Reaction with oxygen Reaction with water Reaction with dilute HCl Reaction with dilute H2SO4
Mg Burns easily
Bright white flame
Vigorous reaction with steam
Very slow reaction with water
Reacts vigorously Reacts vigorously
Ca Difficult to ignite
Red flame
Reacts moderately
Hydroxide formed
Reacts vigorously Reaction is slowed by the formation of a sparingly soluble sulfate layer which coats the metal surface stopping hydrogen bubbles from rising
Sr Difficult to ignite
Red flame
Reacts rapidly
Hydroxide formed
Reacts vigorously Reaction is quickly stopped by the formation of an insoluble sulfate layer on the metal surface
Ba Difficult to ignite
Green flame

Reacts vigorously
Hydroxide formed

Reacts vigorously Reaction is quickly stopped by the formation of an insoluble sulfate layer on the metal surface

Group 2 reactions with oxygen & water chemical equations

Group 2 element Reaction with oxygen Reaction with water
Mg 2Mg (s) + O2 (g) → 2MgO (s)

Mg (s) + H2O (l) → Mg(OH)2 (s) + H2 (g) 
Mg (s) + 2H2O (g) → MgO (s) + H2 (g)

Ca 2Ca (s) + O2 (g) → 2CaO (s) Ca (s) + 2H2O (l) → Ca(OH)2 (s) + H2 (g)
Sr 2Sr (s) + O2 (g) → 2SrO (s)
Sr (s) + O2 (g) → SrO2 (s)
Sr (s) + 2H2O (l) → Sr(OH)2 (aq) + H2 (g)
Ba 2Ba (s) + O2 (g) → 2BaO (s)
Ba (s) + O2 (g) → BaO2 (s)
Ba (s) + 2H2O (l) → Ba(OH)2 (aq) + H2 (g)

Group 2 reactions with dilute hydrochloric acid & dilute sulfuric acid chemical equations

Group 2 element Reaction with dilute HCl Reaction with dilute H2SO4
Mg Mg (s) + 2HCl (aq) → MgCl2 (aq) + H2 (g) Mg (s) + H2SO4 (aq) → MgSO4 (aq) + H2 (g)
Ca Ca (s) + 2HCl (aq) → CaCl2 (aq) + H2 (g) Ca (s) + H2SO4 (aq) → CaSO4 (s) + H2 (g)
Sr Sr (s) + 2HCl (aq) → SrCl2 (aq) + H2 (g) Sr (s) + H2SO4 (aq) → SrSO4 (s) + H2 (g)
Ba Ba (s) + 2HCl (aq) → BaCl2 (aq) + H2 (g) Ba (s) + H2SO4 (aq) → BaSO4 (s) + H2 (g)

  • The reaction of all metals with oxygen follows the following general equation:

2M (s) + O2 (g) → 2MO (s)

Where M is any metal in Group 2

Remember that Sr and Ba also form MO2

  • The reaction of all metals with water follows the following general equation:

M (s) + 2H2O (l) → M(OH)2 (s) + H2 (g)

The exceptions to this general equation are:

    • Be which does not react with water
    • Mg which forms MgO (s) and H2 (g)

  • The reaction of all metals with dilute HCl follows the following general equation:

M(s) + 2HCl(aq) → MCl2(aq) + H2(g)

  • The reaction of all metals with dilute H2SO4 follows the following general equation:

M(s) + H2SO4(aq) → MSO4(aq) + H2(g)

Remember that CaSO4, SrSO4 and BaSO4 are insoluble

Examiner Tip

Learn the general equation for the reaction with oxygen, water and dilute HCl/H2SO4 and the exceptions instead of memorizing the entire table!

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Francesca

Author: Francesca

Expertise: Head of Science

Fran studied for a BSc in Chemistry with Forensic Science, and since graduating taught A level Chemistry in the UK for over 11 years. She studied for an MBA in Senior Leadership, and has held a number of roles during her time in Education, including Head of Chemistry, Head of Science and most recently as an Assistant Headteacher. In this role, she used her passion for education to drive improvement and success for staff and students across a number of subjects in addition to Science, supporting them to achieve their full potential. Fran has co-written Science textbooks, delivered CPD for teachers, and worked as an examiner for a number of UK exam boards.