Group 2, the Alkaline Earth Metals (AQA A Level Chemistry)

Exam Questions

3 hours44 questions
11 mark

The graphs show various properties of the Group 2 elements.

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Which are the correct labels for the y-axes?

 

Graph A

Graph B

A

atomic number

atomic radius

B

melting point

first ionisation energy

C

atomic radius

atomic number

D

first ionisation energy

melting point

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    21 mark

    Pieces of pure solid magnesium and calcium are burned separately with oxygen.

    Pieces of pure solid magnesium and calcium are then reacted separately with cold water.

    Which row correctly describes the observations from these reactions?

     

    Magnesium with oxygen

    Calcium with oxygen

    Magnesium with cold water

    Calcium with cold water

    A

    Red flame

    White flame

    Rapid bubbling

    Slow bubbling

    B

    White flame

    Red flame

    Slow bubbling

    Rapid bubbling

    C

    White flame

    Red flame

    Rapid bubbling

    Slow bubbling

    D

    Red flame

    White flame

    Slow bubbling

    Rapid bubbling

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      31 mark

      Which statements about calcium oxide are correct?

       

      Produced when calcium nitrate is heated

      Reduced by heating with magnesium

      Reacts with cold water

      A

       

       

      B

       

      C

       

      D

       

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        41 mark

        Which descriptions are correct for the solubility of magnesium hydroxide and barium hydroxide?

         

        Magnesium hydroxide

        Barium hydroxide

        A

        Insoluble

        Highly soluble

        B

        Sparingly soluble

        Soluble

        C

        Soluble

        Sparingly soluble

        D

        Highly soluble

        Insoluble

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          51 mark

          Compounds of which Group 2 element are commonly used to neutralise the acidity of soil and remove sulfur dioxide from flue gases?

          • Ba

          • Mg

          • Ca

          • Sr

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          61 mark

          Which is the correct order for the solubility of the Group 2 sulfates from most soluble to least soluble?

           

          most soluble     rightwards arrow     least soluble

          A

          BaSO4

          SrSO4

          CaSO4

          MgSO4

          B

          SrSO4

          BaSO4

          CaSO4

          MgSO4

          C

          MgSO4

          SrSO4

          CaSO4

          BaSO4

          D

          MgSO4

          CaSO4

          SrSO4

          BaSO4

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            71 mark

            Which equation shows the correct reaction of magnesium with cold water?

            • Mg (s) + H2O (g) → MgO (s) + H2 (g)

            • Mg (s) + H2O (l) → MgO (s) + H2 (g)

            • Mg (s) + H2O (g) → Mg(OH)2 (s) + H2 (g)

            • Mg (s) + 2H2O (l) → Mg(OH)2 (s) + H2 (g)

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            81 mark

            Which equation shows the correct reduction of titanium (IV) chloride by magnesium?

            • TiCl4 + 2Mg → 2MgCl2 + Ti

            • TiCl2 + Mg → MgCl2 + Ti

            • TiCl4 + 4Mg → 4MgCl + Ti

            • TiCl4 + Mg → 2MgCl2 + Ti

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            91 mark

            Which is the correct ionic equation for the positive test result of barium chloride with the sulfate ion?

            • BaCl2 + H2SO4 → BaSO4 + 2HCl 

            • BaCl2 + SO42- → BaSO4 + Cl-

            • Ba2++ SO42- → BaSO4 

            • Ba + 2Cl - → BaCl2 

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            101 mark

            Which property would you expect the Group 2 metal beryllium to possess?

            • It is a good electrical conductor

            • It does not react with oxygen

            • It forms a covalent compound with fluorine

            • It forms a soluble hydroxide

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            11 mark

            In agriculture, lime can be added to damp soil to change the pH.

            An ammonium sulfate fertiliser can then be added to the soil, which will result in a chemical reaction.

            Which substances are formed in this reaction?

             

            Sulfuric acid

            Calcium sulfate

            Ammonia

            A

            B

             

            C

             

            D

             

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              21 mark

              Which one of the following statements is true as you move down Group 2?

              • The first ionisation energy increases

              • The atomic radius increases

              • The solubility of the Group 2 hydroxides decreases

              • The solubility of the Group 2 sulfates increases

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              31 mark

              Which Group 2 metal is used to produce titanium by the reduction of titanium (IV) chloride, TiCl4?

              • Magnesium

              • Calcium

              • Strontium

              • Barium

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              41 mark

              Which statement is not correct?

              • Barium has a lower first ionisation energy than strontium

              • Strontium reacts less violently with water than calcium

              • Calcium has a larger atomic radius than magnesium

              • Magnesium hydroxide is less soluble in water than barium hydroxide

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              51 mark

              A laboratory technician discovered an unlabelled bottle containing a pure white solid.

              After dissolving the solid in water, tests were completed on the unknown solid and it was identified as barium chloride.

              What are the correct observations for the chemical reactions of the barium chloride solution?

               

              Added to HCl (aq)

              Added to H2SO4 (aq)

              Added to AgNO3 (aq)

              A

              White precipitate forms

              Colourless solution forms

              Colourless solution forms

              B

              No visible change

              White precipitate forms

              Colourless solution forms

              C

              White precipitate forms

              Colourless solution forms

              White precipitate forms

              D

              No visible change

              White precipitate forms

              White precipitate forms

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                61 mark

                Which statement about the general trend in melting points for the Group 2 metals is correct?

                • The melting point increases as you move down Group 2 because there are more delocalised electrons in the metallic structure

                • The melting point decreases as you move down Group 2 because the force of attraction between the layers of positive ions and delocalised electrons is less

                • The melting point increases as you move down Group 2 because more energy is required to break the metallic bonds

                • The melting point decreases as you move down Group 2 because the van der Waals forces are larger due to larger metal atoms within the structure

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                71 mark

                The Group 2 oxides all produce alkaline solutions when added to water.

                Which Group 2 oxide produces a saturated solution with the highest pH?

                • SrO (aq)

                • MgO (aq)

                • CaO (aq)

                • BaO (aq)

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                81 mark

                Lime mortar is made by mixing quicklime with water and sand. Over time, lime mortar hardens in air. 

                Dilute hydrochloric acid reacts with both fresh and old lime mortar. Only old lime mortar will produce effervescence

                Which reaction shows the change over time for the formation of old lime mortar from fresh lime mortar?

                • CaO + CO2 → CaCO3

                • CaO + H2O → Ca(OH)2

                • Ca(OH)2 → CaO + H2O

                • Ca(OH)2 + CO2 → CaCO3 + H2O

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                91 mark

                Barium chloride solution was added to a solution of calcium sulfate until no more precipitate formed. The mixture was filtered.

                Which ions are in the filtrate?

                 

                Ba2+

                Ca2+

                Cl- 

                SO42-

                A

                 

                 

                B

                 

                 

                C

                   

                D

                 

                 

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                  101 mark

                  Which is the correct use of a Group 2 compound?

                  • MgO is commonly used in agriculture to reduce soil acidity 

                  • Ca(OH)2 is used as an indigestion remedy

                  • SrCO3 is used in fireworks and flares

                  • BaCl2 is used as barium meals in medicine

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                  11 mark

                  When equal volumes of saturated solutions of barium hydroxide and calcium hydroxide are mixed, a white precipitate, Y, forms.

                  The mixture is filtered, and carbon dioxide is bubbled through the filtrate, producing a second white precipitate, Z.

                  What are Y and Z?

                   

                  Y

                  Z

                  A

                  Ba(OH)2

                  Mostly Ca(OH)2

                  B

                  Ba(OH)2

                  Mostly CaCO3

                  C

                  Ca(OH)2

                  Mostly BaCO3

                  D

                  Ca(OH)2

                  Mostly Ba(OH)2

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                    21 mark

                    A student performed experiments on chemicals containing an unknown alkaline earth metal, M.

                    The student’s results and observations are shown.

                    Test

                    Observation

                    The metal hydroxide, M(OH)2, is added to water

                    The metal hydroxide dissolves forming a colourless solution

                    The metal sulfate, MSO4, is added to water

                    The metal sulfate does not dissolve, leaving a white suspension

                    The freshly cut metal is left open to the air

                    The metal readily oxidises

                    What is the identity of the unknown alkaline earth metal, M?

                    • Beryllium

                    • Barium 

                    • Calcium 

                    • Magnesium 

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                    31 mark

                    The first ionisation energies and reactions with oxygen for magnesium and barium are compared below.

                    Which set of statements, comparing magnesium and barium, are correct?

                     

                    Mg first ionisation energy

                    Ba first ionisation energy

                    Mg reaction with oxygen

                    Ba reaction with oxygen

                    A

                    Lower

                    Higher

                    Faster

                    Slower

                    B

                    Lower

                    Higher

                    Slower

                    Faster

                    C

                    Higher

                    Lower

                    Faster

                    Slower

                    D

                    Higher

                    Lower

                    Slower

                    Faster

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                      41 mark

                      A laboratory technician discovered three unlabelled bottles, each containing one pure white solid. The bottles were known to contain different Group 2 metal salts.

                      Tests were completed on all three unknown solids or, if the compound was soluble, on the aqueous solution. The results are shown in the table.

                      Test

                      1

                      2

                      3

                      Added to water

                      Dissolves

                      Insoluble

                      Dissolves

                      Added to HCl (aq)

                      Heat released

                      Solution remains colourless

                      Carbon dioxide released

                      Colourless solution forms

                      Solution remains colourless

                      Added to NaOH (aq)

                      No visible change

                      Solid remains insoluble

                      Solution forms a white precipitate

                      Added to H2SO4 (aq)

                      Solution forms a white precipitate

                      Carbon dioxide released

                      White solid remains

                      No visible change

                      What are compounds 1, 2 and 3?

                       

                      1

                      2

                      3

                      A

                      Barium carbonate

                      Magnesium sulfate

                      Strontium hydroxide

                      B

                      Strontium hydroxide

                      Barium carbonate

                      Magnesium sulfate

                      C

                      Magnesium sulfate

                      Strontium hydroxide

                      Barium carbonate

                      D

                      Magnesium sulfate

                      Barium carbonate

                      Strontium hydroxide

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                        51 mark

                        The salts of Group 2 metals have a variety of real world applications.

                        Which row contains the correct identities of Group 2 elements and compounds for the applications?

                         

                        Treat acid indigestion

                        Extracting titanium from TiCl4

                        Removing SO2 from flue gases

                        Reducing acidity in soil

                        A

                        Calcium carbonate

                        Calcium

                        Calcium oxide

                        Slaked lime

                        B

                        Magnesium sulfate

                        Sodium

                        Calcium hydroxide

                        Limestone powder

                        C

                        Magnesium hydroxide

                        Magnesium

                        Calcium oxide

                        Slaked lime

                        D

                        Calcium hydroxide

                        Magnesium

                        Calcium carbonate

                        Quicklime

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                          61 mark

                          Why does the melting point of the Group 2 metals decrease as you move down the group?

                          • The atomic radius increases

                          • The attraction between the anions and delocalised electrons decreases

                          • The amount of shielding increases

                          • The attraction between the cations and delocalised electrons decreases

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                          71 mark

                          Which graph correctly shows the melting points of Group 2 metals?

                          • rQ6s~msa_3

                          • TTvG-N2-_4

                          • -QiaPNG9_5

                          • UerdJmOf_6

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                          81 mark

                          Which statement is not correct?

                          • Beryllium will not react with cold water

                          • Strontium has a larger atomic radius than calcium

                          • Barium chloride does not dissolve in cold water

                          • Radium is violently reactive with water

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                          91 mark

                          Magnesium can react with water.

                          With cold water, bubbles of gas form on the surface of the magnesium ribbon. A white protective layer slowly forms on the surface of the magnesium and stops it reacting.

                          What is the correct equation for the reaction of magnesium with water vapour?

                          • Mg (s) + 2H2O (l) → Mg(OH)2 (s) + H2 (g)

                          • Mg (s) + H2O (g) → MgO (s) + H2 (g)

                          • Mg (s) + H2O (l) → MgO (s) + H2 (g)

                          • Mg (s) + H2O (g) → Mg(OH)2 (s) + H2 (g)

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                          101 mark

                          Barium chloride solution was acidified with nitric acid. The acidified barium chloride solution was added to a solution of magnesium sulfate. When no more precipitate formed, the mixture was filtered.

                          Where is each ion after filtration of the completed reaction?

                           

                          Mg2+

                          Ba2+

                          Cl-

                          NO3-

                          SO42-

                          A

                          Filtrate

                          Residue

                          Filtrate

                          Filtrate

                          Residue

                          B

                          Residue

                          Filtrate

                          Residue

                          Filtrate

                          Filtrate

                          C

                          Filtrate

                          Residue

                          Filtrate

                          Residue

                          Filtrate

                          D

                          Residue

                          Filtrate

                          Residue

                          Filtrate

                          Residue

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