Melting Point Trend (AQA A Level Chemistry)

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Melting Point Trend

  • The melting points of the oxides vary significantly across Period 3 and show a clear trend
  • Melting point is a clear indication of the forces of attraction which exist between ions, atoms or molecules

 

A graph to show the melting points of the Period 3 Oxides

 

Ionic Oxides

  • The graph starts off showing the melting points of the ionic oxides
    • Sodium oxide
    • Magnesium oxide
    • Aluminium oxide

  • These are ionic oxides because the bonding exists between metals and non metals
  • They have giant lattice structures and thus, high melting points

Giant Covalent Oxides

  • The graph then shows a giant covalent oxide
    • Silicon dioxide

  • This is covalent because both silicon and oxygen are non metals
  • The millions of covalent bonds within this giant structure are extremely strong, and thus it has a high melting point
  • Giant covalent structures can also be called macromolecules or giant molecules

Simple Covalent Oxides

  • The graph then shows a significant drop in melting point, as we reach the simple covalent oxide molecules
    • Phosphorus(V) oxide
    • Sulfur dioxide
    • Sulfur trioxide

  • These are small molecules with only weak intermolecular forces of attraction between them
  • Sulfur dioxide and sulfur trioxide are both gases at room temperature, because both their melting point and boiling point are so low
    • Sulfur trioxide, SO3, has a slightly higher melting point than sulfur dioxide, SO2, because of the increase in intermolecular forces between the slightly larger SO3 molecules

Summary Table of the Physical Properties of the Period 3 Oxides

 

Examiner Tip

Make sure that you can state and explain the link between the physical properties of the Period 3 Oxides and their structure and bonding!

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Stewart

Author: Stewart

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Exam Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.