Melting Point Trend
- The melting points of the oxides vary significantly across Period 3 and show a clear trend
- Melting point is a clear indication of the forces of attraction which exist between ions, atoms or molecules
A graph to show the melting points of the Period 3 Oxides
Ionic Oxides
- The graph starts off showing the melting points of the ionic oxides
- Sodium oxide
- Magnesium oxide
- Aluminium oxide
- These are ionic oxides because the bonding exists between metals and non metals
- They have giant lattice structures and thus, high melting points
Giant Covalent Oxides
- The graph then shows a giant covalent oxide
- Silicon dioxide
- This is covalent because both silicon and oxygen are non metals
- The millions of covalent bonds within this giant structure are extremely strong, and thus it has a high melting point
- Giant covalent structures can also be called macromolecules or giant molecules
Simple Covalent Oxides
- The graph then shows a significant drop in melting point, as we reach the simple covalent oxide molecules
- Phosphorus(V) oxide
- Sulfur dioxide
- Sulfur trioxide
- These are small molecules with only weak intermolecular forces of attraction between them
- Sulfur dioxide and sulfur trioxide are both gases at room temperature, because both their melting point and boiling point are so low
- Sulfur trioxide, SO3, has a slightly higher melting point than sulfur dioxide, SO2, because of the increase in intermolecular forces between the slightly larger SO3 molecules
Summary Table of the Physical Properties of the Period 3 Oxides
Examiner Tip
Make sure that you can state and explain the link between the physical properties of the Period 3 Oxides and their structure and bonding!